![](http://static.xuejinqu.com/qimg/014/014180be1d27e1d88e0d77ac3b3f6655.png)
N2和H2生成NH3的反应为:
![](http://static.xuejinqu.com/qimg/ae9/ae9afa911c676e39af2d9f3bc42e0939.png)
![](http://static.xuejinqu.com/qimg/c1d/c1da22e63296ca27f7a073a711490e33.png)
![](http://static.xuejinqu.com/qimg/a1d/a1dcfb8e110a534ab6f83ab79ca64dc2.png)
在Fe催化剂作用下的反应历程为(*表示吸附态)
化学吸附:N2(g)→2N*;H2(g)
![](http://static.xuejinqu.com/qimg/a1d/a1dcfb8e110a534ab6f83ab79ca64dc2.png)
表面吸附:N*+H*
![](http://static.xuejinqu.com/qimg/a1d/a1dcfb8e110a534ab6f83ab79ca64dc2.png)
![](http://static.xuejinqu.com/qimg/a1d/a1dcfb8e110a534ab6f83ab79ca64dc2.png)
![](http://static.xuejinqu.com/qimg/a1d/a1dcfb8e110a534ab6f83ab79ca64dc2.png)
脱附:NH3*
![](http://static.xuejinqu.com/qimg/a1d/a1dcfb8e110a534ab6f83ab79ca64dc2.png)
其中,N2的吸附分解反应活化能高、速率慢,决定了合成氨的整体反应速率。
请回答:
(1)利于提高合成氨平衡产率的条件有
A.低温B.高温C.低压D.高压E.催化剂
(2)标准平衡常数
![](http://static.xuejinqu.com/qimg/ddc/ddc5a890266806d6cfdb5204fc44ac74.png)
![](http://static.xuejinqu.com/qimg/2af/2af3b3fd515bf559013d44c4046bf4c9.png)
![](http://static.xuejinqu.com/qimg/44a/44a0ec8f7995f1c8ea089570ba57055c.png)
![](http://static.xuejinqu.com/qimg/9b1/9b175b87df8052e4a2cfbc0712080491.png)
![](http://static.xuejinqu.com/qimg/cb7/cb7380e0e30a383fb7049ddf7ba59dc1.png)
![](http://static.xuejinqu.com/qimg/44a/44a0ec8f7995f1c8ea089570ba57055c.png)
![](http://static.xuejinqu.com/qimg/d8a/d8a2a30ce82ee459687fb18347f3d1fb.png)
![](http://static.xuejinqu.com/qimg/d8a/d8a2a30ce82ee459687fb18347f3d1fb.png)
①N2和H2起始物质的量之比为1:3,反应在恒定温度和标准压强下进行,NH3的平衡产率为ω,则
![](http://static.xuejinqu.com/qimg/719/7191f1726fcf632274b441d6c3d6c6d4.png)
②图中可以示意标准平衡常数K随温度T变化趋势的是
![](http://static.xuejinqu.com/qimg/13d/13d262a02ec601d5f1f12d587a9e56c5.png)
(3)实际生产中,常用工艺条件:Fe作催化剂,控制温度773K、压强3.0×107Pa,原料气中N2和H2物质的量之比为1:2.8
①分析说明原料气中N2过量的理由
②关于合成氨工艺的下列理解,正确的是
A.合成氨反应在不同温度下的△H和△S都小子零
B.控制温度(773K)远高于室温,是为了保证尽可能高的平衡转化率和快的反应速率
C.当温度、压强一定时,在原料气(N2和H2的比例不变)中添加少量惰性气体,有利于提高平衡转化率
D.基于NH3有较强的分子间作用力可将其液化,不断将液氨移去,利于反应正向进行
E.分离空气可得N2,通过天然气和水蒸气转化可得H2,原料气须经过净化处理,以防止催化剂中毒和安全事故发生
(二)高铁酸钾(K2FeO4)可用作水处理剂口某同学通过“化学一电解法”探究K2FeO4的合成,其原理如图2所示.接通电源,调节电压,将一定量C12通入KOH溶液,然后滴入含Fe3+的溶液,控制温度,可制得K2FeO4
(1)请写出“化学法”得到FeO42一的离子方程式
(2)请写出阳极的电极反应式(含FeO42-)
![](http://static.xuejinqu.com/qimg/169/16954e27d0db9738c6d46b6f99edf1f7.png)
![](http://static.xuejinqu.com/images/y-prise.png)
同类型试题
![](http://static.xuejinqu.com/images/medal.png)
y = sin x, x∈R, y∈[–1,1],周期为2π,函数图像以 x = (π/2) + kπ 为对称轴
y = arcsin x, x∈[–1,1], y∈[–π/2,π/2]
sin x = 0 ←→ arcsin x = 0
sin x = 1/2 ←→ arcsin x = π/6
sin x = √2/2 ←→ arcsin x = π/4
sin x = 1 ←→ arcsin x = π/2
![](http://static.xuejinqu.com/images/avatar.png)
![](http://static.xuejinqu.com/images/avatar.png)
y = sin x, x∈R, y∈[–1,1],周期为2π,函数图像以 x = (π/2) + kπ 为对称轴
y = arcsin x, x∈[–1,1], y∈[–π/2,π/2]
sin x = 0 ←→ arcsin x = 0
sin x = 1/2 ←→ arcsin x = π/6
sin x = √2/2 ←→ arcsin x = π/4
sin x = 1 ←→ arcsin x = π/2
![](http://static.xuejinqu.com/images/avatar.png)
![](http://static.xuejinqu.com/images/avatar.png)